ON THE ABSORPTION SPECTRUM OF C60 IN THE VISIBLE SPECTRAL REGION

ABSTRACT

A complete (720–380?nm), strong visible absorption spectrum (OD₅₉₈=1.6) for C₆₀ in a decalin/methylcyclohexane inert matrix at 77?K is reported for the first time. The structure of this spectrum allows one to construct an acceptable approximation to the gas-phase spectrum for this substance at a low temperature. The 0–0 component of the S₀→S₁ transition in the gas phase at a low temperature was estimated to be at about 635?nm.