Radiation-induced grafting of glycidyl methacrylate onto cotton fabric waste and its modification for anchoring hazardous wastes from their solutions |
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Authors: | Hesham H. Sokker Sayed M. Badawy Ehab M. Zayed Faten A. Nour Eldien Ahmad M. Farag |
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Affiliation: | 1. National Center for Radiation Research & Technology, Cairo, Egypt;2. National Center for Clinical and Environmental Toxicology, Faculty of Medicine, Cairo University, Egypt;3. Department of Chemistry, Faculty of Science, Cairo University, Giza 12613, Egypt |
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Abstract: | Ion exchange adsorbents based on cellulosic fabric wastes carrying sulfonic acid and amine functional groups were synthesized by radiation-induced graft polymerization of glycidyl methacrylate (GMA) with subsequent chemical modification of the epoxy groups of poly-GMA graft chains with sodium sulfite/H2SO4 and triethylamine, respectively. The conversion of epoxy groups into the functional groups was investigated. Factors affecting on grafting process such as radiation dose, monomer concentration and solvent were studied. The synthesized adsorbent and its applications in the removal of different types of hazardous pollutants e.g. acidic dye, cobalt, dichromate and phenols from aqueous solution were also studied. |
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Keywords: | Radiation-induced grafting Adsorption Glycidyl methacrylate Acidic dye Cotton fabric waste |
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