Catalytic Effects of Minerals on NOx Emission from Coal Combustion |
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Authors: | M. Y. Yao D. F. Che |
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Affiliation: | School of Energy and Power Engineering, Xi'an Jiaotong University , Xi'an, China |
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Abstract: | Abstract The catalytic effects of inherent mineral matters on NO x emissions from coal combustion have been investigated by a thermo-gravimetric analyzer (TGA) equipped with a gas analyzer. The effect of demineralization and the individual effect of Na, K, Ca, Mg, and Fe on the formation of NO x are studied as well as the combined catalytic effects of Ca + Na and Ca + Ti. Demineralization causes more Fuel-N to retain in the char, and reduction of NO x mostly. But the mechanistic effect on NO x formation varies from coal to coal. Ca and Mg promote NO x emission. Na, K, Fe suppress NO x formation to different extents. The effect of transition element Fe is the most obvious. The combination of Ca + Na and Ca + Ti can realize the simultaneous control of sulfur dioxide and nitrogen oxides emissions. |
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Keywords: | catalytic demineralization NO x emissions simultaneous control |
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