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Electrochemical synthesis of polyacetylene tetrachloroferrate [CH(FeCl4)y]x and tetrachloroaluminate [CH(AlCl4)y]x |
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| Authors: | J. Przyluski, M. Zag rska, K. Conder,A. Pro&#x |
| Affiliation: | Department of Chemistry, Technical University of Warsaw, 00 664, Warsaw, Noakowskiego 3, Poland |
| Abstract: | Polyacetylene can be electrochemically oxidized in LiClFeCl3 nitromethane and LiClAlCl3 nitromethane solutions to give a highly conducting (500 ohm−1 cm−1) polymer exhibiting p-type conductivity. The limiting composition obtainable in the electrolysis can be expressed by the following formula: [CH(MCl4)0.05]x where M = FeAl. |
| Keywords: | Conducting polymers polyacetylene electrochemical doping acceptor type doping metal halide doping |
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