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Bi2O3对烧结LiZn铁氧体性能的影响
引用本文:余忠,陈代中,兰中文,蒋晓娜,刘保元.Bi2O3对烧结LiZn铁氧体性能的影响[J].无机材料学报,2007,22(6):1173-1177.
作者姓名:余忠  陈代中  兰中文  蒋晓娜  刘保元
作者单位:电子科技大学,电子薄膜与集成器件国家重点实验室,成都,610054
摘    要:采用氧化物陶瓷工艺制备了掺Bi2O3的Li0.4Zn0.2Fe24O4铁氧体.用XRD、SEM、密度测试和磁性能表征,研究了Bi2O3对LiZn铁氧体性能的影响.结果表明:Bi2O3能有效抑制烧结过程中的锂挥发,促进固相反应,降低烧结温度,但过多的Bi2O3会阻止晶粒生长;适量掺杂Bi2O3可以提高LiZn铁氧体的饱和磁感应强度和矩形比,降低铁氧体的矫顽力.

关 键 词:LiZn铁氧体  掺Bi2O3  晶粒生长  锂挥发
文章编号:1000-324X(2007)06-1173-05
收稿时间:2006-10-18
修稿时间:2006-10-18

Effect of Bi2O3 on Properties of Lithium-Zinc Ferrite
YU Zhong,CHEN Dai-Zhong,LAN Zhong-Wen,JIANG Xiao-Na,LIU Bao-Yuan.Effect of Bi2O3 on Properties of Lithium-Zinc Ferrite[J].Journal of Inorganic Materials,2007,22(6):1173-1177.
Authors:YU Zhong  CHEN Dai-Zhong  LAN Zhong-Wen  JIANG Xiao-Na  LIU Bao-Yuan
Affiliation:State Key Lab of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054, China
Abstract:The lithium-zinc ferrite doped with Bi2O3 was prepared by the conventional oxide ceramic process. The effect of Bi2O3 on properties of lithium-zinc ferrite was investigated by means of characterizing the phase component and fracture surface micrograph by X-ray diffraction (XRD) and scanning electron microscope (SEM), density by Archimedean method, and magnetic properties by B-H analyzer. The results show that Bi2O3 can effectively bate the volatilization of lithium, promote solid state reaction and decrease the sintering temperature, but excessive Bi2O3 can restrain the crystal grain growth during sintering process. An optimal amount of Bi2O3 is beneficial to increase the saturation magnetic induction Bs and squareness Br/Bs, and decrease the coercive force Hc of lithium-zinc ferrite.
Keywords:lithium-zinc ferrite  Bi2O3-dope  crystal grain growth  lithium-volatilization
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