| 金属席夫碱催化分子氧氧化环己烷的研究 |
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| 引用本文： | 李伟,王志亮. 金属席夫碱催化分子氧氧化环己烷的研究[J]. 广东化工, 2014, 0(3): 16-17,13 |
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| 作者姓名： | 李伟 王志亮 |
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| 作者单位： | 山东科技大学化学与环境工程学院,山东青岛,266590 |
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| 摘 要： | 采用两步法合成了两类共18种金属席夫碱配合物,将其用于催化环己烷的氧化反应。结果表明:金属席夫碱配合物在温和条件下能有效催化环己烷的反应,生成目的产物;双核金属席夫碱催化效果较单核好。
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| 关 键 词： | 金属席夫碱 环己烷 催化氧化 |
Study on Metal Schiff Base Catalyzed Cyclohexane Oxidation with Molecular Oxygen |
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| Li Wei,Wang Zhiliang. Study on Metal Schiff Base Catalyzed Cyclohexane Oxidation with Molecular Oxygen[J]. Guangdong Chemical Industry, 2014, 0(3): 16-17,13 |
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| Authors: | Li Wei Wang Zhiliang |
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| Affiliation: | (College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China) |
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| Abstract: | Eighteen kinds of metal Schiff Base complexes with two different structures were prepared by means of two step method. The experiments for the cyclohexane catalyzed by the catalysts were carried out. The result displays a significant catalytic effect on the cyclohexane product yield under mild reaction conditions. Compared to mononuclear metal Schiff Base, binuclear metal Schiff Base have the better catalytic activity. |
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| Keywords: | metalSchiffBase cyclohexane： catalytic oxidation |
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