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以三氧化二锑为协效剂的复合阻燃剂对MVQ硫化胶阻燃性能的影响
引用本文:亢庆卫,罗权焜.以三氧化二锑为协效剂的复合阻燃剂对MVQ硫化胶阻燃性能的影响[J].橡胶工业,2004,51(11):651-655.
作者姓名:亢庆卫  罗权焜
作者单位:华南理工大学,材料科学与工程学院,广东,广州,510640
摘    要:分别研究硼酸锌/三氧化二锑、氢氧化铝/三氧化二锑和三氧化钼/三氧化二锑并用体系对甲基乙烯基硅橡胶(MVQ)硫化胶阻燃性能和物理性能的影响。结果表明,硼酸锌/三氧化二锑并用体系可有效提高MVQ硫化胶的阻燃性能,并能保持较好的物理性能;氢氧化铝/三氧化二锑并用体系的阻燃效果十分显著,但MVQ硫化胶的发烟量稍大;三氧化钼/三氧化二锑并用体系虽可减小MVQ硫化胶的发烟量,但阻燃效果不明显,且硫化胶的物理性能受损严重。

关 键 词:三氧化二锑  硼酸锌  氢氧化铝  三氧化钼  甲基乙烯基硅橡胶  阻燃性能  物理性能
文章编号:1000-890X(2004)11-0651-05
修稿时间:2004年5月9日

Effects of compound flame retardants with Sb2O3 on flame retardance of MVQ vulcanizate
KANG Qing-wei and LUO Quan-kun.Effects of compound flame retardants with Sb2O3 on flame retardance of MVQ vulcanizate[J].China Rubber Industry,2004,51(11):651-655.
Authors:KANG Qing-wei and LUO Quan-kun
Affiliation:South China University of Technology and South China University of Technology
Abstract:The effects of various compound flame retardants with Sb_2O_3,such as Zn_3(BO_3)_2/Sb_2O_3,Al(OH)_3/Sb_2O_3 and MoO_3/Sb_2O_3,on the flame retardance and physical properties of MVQ vulcanizate were investigated.The results showed that the flame retardance of MVQ vulcanizate improved significantly by using Zn_3(BO_3)_2/Sb_2O_3,while the physical properties changed little;the better flame retardance was obtained by using Al(OH)_3/Sb_2O_3,but MVQ vulcanizate would generate more smoke;and the smoke generated by MVQ vulcanizate could be reduced by MoO_3/Sb_2O_3,but the flame retardance didn't improve significantly,and the physical properties of vulcanizate deteriorated severely.
Keywords:Sb_2O_3  Zn_3(BO_3)_2  Al(OH)_3  MoO_3  MVQ  flame retardance
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