Assembly of a water-insoluble strontium metal–organic framework with luminescent properties |
| |
| Authors: | Sheng-Han Lo Hsin-Kuan Liu Jun-Xiang Zhan Wei-Cheng Lin Ching-Che Kao Chia-Her Lin Vítězslav Zima |
| |
| Affiliation: | aDepartment of Chemistry, Chung Yuan Christian University, 200, Chung Pei Road, Chung Li, Taiwan;bJoint Laboratory of Solid State Chemistry IMC AS CR, v.v.i. and University of Pardubice, Studentská 84, 532 10 Pardubice, Czech Republic |
| |
| Abstract: | A new strontium metal–organic framework, Sr2(BTEC)(H2O)4]?2H2O (1) (H4BTEC = benzene-1,2,4,5-tetracarboxylic acid), has been successfully synthesized by mixing the starting reagents. The single-crystal structure analysis showed that compound 1 displayed three-dimensional structures containing inorganic motifs with two-dimensional layers pillar-connected through organic linkers and forming water-coordinated neutral framework. Further studies revealed that compound 1 was insoluble in water and that it emitted strong luminescence at approximately 437 nm after dehydration. |
| |
| Keywords: | Strontium complex Metal&ndash organic framework Luminescent Water-insoluble |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
