Synthesis of tertiary poly(amido-amine)s with amido- and amino-groups randomly arranged along the macromolecular chain |
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| Authors: | L Rusconi MC Tanzi P Ferruti L Angiolini R Barbucci M Casolaro |
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| Affiliation: | Istituto di Chimica Industriale del Politecnico, Piazza L. da Vinci 32, 20133 Milano, Italy;Istituto di Chimica degli Intermedi dell'' Università, Viale Risorgimento 4, 40136 Bologna, Italy;Istituto di Chimica Generale dell'' Università, Pian dei Mantellini 44, 53100 Siena, Italy |
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| Abstract: | A new synthesis of poly(amido-amine)s from bis (secondary amine)s and acryloyl chloride has been studied, leading to polymers in which the amido- and amino-groups are randomly arranged along the macromolecular chain. A poly(amido-amine) based on piperazine, chosen as the mother compound, has been fully characterized by 13C n.m.r. as well as by identification and quantitative evaluation of its hydrolysis products. |
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| Keywords: | Poly(amido-amine)s tertiary random bis (secondary amines) acryloyl chloride |
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