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Y_2O_3:Eu~(3+)@Gd_2O_3核壳结构发光材料的制备与浓度猝灭
引用本文:刘桂霞,白海英,董相廷,王进贤. Y_2O_3:Eu~(3+)@Gd_2O_3核壳结构发光材料的制备与浓度猝灭[J]. 硅酸盐学报, 2011, 39(9): 1411-1417
作者姓名:刘桂霞  白海英  董相廷  王进贤
作者单位:长春理工大学化学与环境工程学院,长春,130022
基金项目:国家自然科学基金(51072026); 吉林省科技发展计划(20090528)资助项目
摘    要:采用均相沉淀法制备均匀球形的Y2O3:Eu3+@Gd2O3核壳结构纳米发光材料,用X射线衍射、红外光谱、扫描电镜、X射线光电子能谱及荧光光谱等表征样品的形貌、结构及发光性能。结果表明:Y2O3:Eu3+表面成功包覆了Gd2O3,包覆后仍为均匀的球形,包覆层厚度约为5nm;包覆前后样品的猝灭浓度均为7%(摩尔分数),包覆...

关 键 词:氧化钇  氧化钆  核壳结构  发光  浓度猝灭

Preparation and Concentration Quenching of Y_2O_3:Eu~(3+)@Gd_2O_3 Core-shell Structural Luminescence Materials
LIU Guixia,BAI Haiying,DONG Xiangting,WANG Jinxian. Preparation and Concentration Quenching of Y_2O_3:Eu~(3+)@Gd_2O_3 Core-shell Structural Luminescence Materials[J]. Journal of The Chinese Ceramic Society, 2011, 39(9): 1411-1417
Authors:LIU Guixia  BAI Haiying  DONG Xiangting  WANG Jinxian
Affiliation:LIU Guixia,BAI Haiying,DONG Xiangting,WANG Jinxian(School of Chemistry and Environmental Engineering,Changchun University of Science and Technology,Changchun 130022,China)
Abstract:Core-shell structural luminescence nanomaterials(Y2O3:Eu3+@Gd2O3) were prepared by homogeneous precipitation method.Samples were characterized by X-ray diffraction,Fourier transform infrared spectroscopy,scanning electron microscopy,X-ray photoelectron energy spectroscopy,and photoluminescence spectroscopy.Results show that Gd2O3 layer is successfully coated on surface of Y2O3:Eu3+.The coated samples are still uniform spheres,and thickness of the coated layer is about 5 nm.Quenching content in mole of the s...
Keywords:yttria  gadolinia  core-shell structrue  luminescence  concentration quenching  
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