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哈龙替代品全氟己酮及中间体全氟丙酰氟合成综述
引用本文:白占旗,倪航,柳彩波.哈龙替代品全氟己酮及中间体全氟丙酰氟合成综述[J].有机氟工业,2010(4):30-32,45.
作者姓名:白占旗  倪航  柳彩波
作者单位:浙江蓝天环保高科技有限公司ODS替代品研究所,浙江杭州310023
摘    要:全氟己酮是哈龙灭火剂的清洁替代品,具有优异的环境和使用性能。对其合成方法进行了介绍和分析,指出了以六氟丙烯为原料的合成工艺具有工业化前景。并对六氟丙烯工艺的重要中间体全氟丙酰氟的合成方法进行了综述。

关 键 词:全氟己酮  全氟丙酰氟  环氧化  催化重排

Review on Synthesis of Perfluoro-2-Methylpentane-3-one and Perfluoropropionyl Fluoride
Bai Zhanqi,Ni Hang,Liu Caibo.Review on Synthesis of Perfluoro-2-Methylpentane-3-one and Perfluoropropionyl Fluoride[J].Organo-Fluorine Industry,2010(4):30-32,45.
Authors:Bai Zhanqi  Ni Hang  Liu Caibo
Affiliation:(Zhejiang Lantian Enviroment Protection High-tech co.,Ltd.Hangzhou 310023,Zhejiang)
Abstract:Perfluoro-2-methylpentane-3-one is a halon alternative.Its properties on ozone depletion potential(ODP),global warming potential(GWP) and the atmospheric lifetime are superior to halon fire extinguisher and other halon alternatives.This paper is a review on the synthesis of perfluorinated ketone and perfluoropropionyl fluoride,and indicates that the route of hexafluoropropene as a material may be an industrial strategy.
Keywords:perfluoroketone perfluoropropionyl fluoride epoxidation catalytic rearrangement
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