生物质炭基材料在有机催化转化中的应用

近年来，生物质因具有富碳可再生、储量丰富、环境友好、价格低廉等特点被作为原料广泛应用于制备生物质炭基材料。本文综述了以生物质为原料衍生炭基材料作为催化剂在有机转化反应中的相关研究进展，重点介绍了杂原子掺杂、金属杂化策略所制备炭基催化材料在液相催化加氢、氧化、偶联等有机转化反应中的催化性能，进而阐明了炭基催化剂与催化活性之间的构效关系。最后，本文总结了生物质炭基催化剂在有机催化反应中的优势，指出了目前生物质衍生炭基催化剂材料合成和有机转化研究领域面临的挑战，并对此领域的未来发展趋势进行了分析与展望。

Biomass-derived carbon materials for organic transformations

Recently, biomass has been intensively employed as an ideal carbon raw material to prepare carbon materials due to its rich carbon, natural abundance and renewability, environmental friendliness, and low-cost. This review summarizes the recent progress in design and preparation of carbon materials derived from various biomass feedstocks and in their application as catalysts for organic transformations. The focus was placed on those carbon catalysts prepared by heteroatoms-doping and metal-hybridization strategies and their applications in liquid-phase catalytic hydrogenation, oxidation, and coupling reactions. Meanwhile, the correlation between catalyst's structure and catalytic performance was elucidated accordingly. Lastly, the merits of biomass-based carbon catalysts in organic synthesis were summarized, and the current challenging and future perspectives for the design and preparation of biomass-based catalysts and their applications in organic transformation are provided.