| C_5-C_8正构烷烃直接转化为芳香烃的研究 |
| |
| 引用本文： | 刘路加,董群,武显春,张逢玉.C_5-C_8正构烷烃直接转化为芳香烃的研究[J].石油化工,1993(6). |
| |
| 作者姓名： | 刘路加 董群 武显春 张逢玉 |
| |
| 作者单位： | 大庆石油学院石油化工系，大庆石油学院石油化工系，大庆石油学院石油化工系，大庆石油学院石油化工系 黑龙江安达市 151400，黑龙江安达市 151400，黑龙江安达市 151400，黑龙江安达市 151400 |
| |
| 摘 要： | 用常规浸渍法制备出GaZnHZSM-5催化剂,通过对正己烷的芳构化试验表明其活性高于HZM-5和用常规浸渍法制备的GaHZSM-5、ZnHZSM-5催化剂。用GaZnHZSM-5催化剂对正戊烷、正己烷、正庚烷、正辛烷分别进行芳构化性能考察,在常压、500℃、重时空速10小时~(-1)的比较缓和的反应条件下,碳数越高的烷烃芳构化效果越佳,正戊烷的芳烃收率只达22.91％。在常压、550℃、重时空速0.5小时~(-1)的比较苛刻的反应条件下,正戊烷转化为芳烃的收率可提高到42.12％,C_6、C_7、C_8烷烃的芳烃收率依次为53.21％、55.72％、56.75％。
|
| 关 键 词： | 芳构化 正构烷烃 分子筛 |
An Investigation on the Direct Converion of C_5--C_8 Paraffins to Aromtics |
| |
| Liu Lujia,Dong Qun,Wu Xianchun,Zhang Fengy Petrochemical Technology.An Investigation on the Direct Converion of C_5--C_8 Paraffins to Aromtics[J].Petrochemical Technology,1993(6). |
| |
| Authors: | Liu Lujia Dong Qun Wu Xianchun Zhang Fengy Petrochemical Technology |
| |
| Affiliation: | Liu Lujia,Dong Qun,Wu Xianchun,Zhang Fengy Petrochemical Technology Department,Daqing Petroleum Institute. Anda 151400 |
| |
| Abstract: | A GaZnHZSM-5 catalyst is prepared by conventional impregnation method. Its aromatization activity for hexane conversion is higher than GaHZSM-5 and ZnHZSM-5 catalysts prepared by the same method. A series of investigation on the conversion of pentane, hexane, heptane and octane to aromatics have been conducted. Under the mild reaction conditions of atmospheric presure, 500℃ and is WHSv=1.0h~(-1), the paraffin having longer carbon chain produce more aromatics, the aromatic yield of pentane is only 22.91%. Under the more severe reaction conditions of atmospheric pressure, 550℃ and WHSV=0.5h~(-1), the aromatic yield of pentane rises to 42.12%, the aromatic yield ofehexan, heptane and octane are 53.21%, 55.27% and 56.75%, respectvely. |
| |
| Keywords: | aromatization paraffins zeolite |
| 本文献已被 CNKI 等数据库收录！ |
|
