含叔丁醇体系的汽液平衡测定和关联 |
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引用本文: | 陈新志 陈钟秀. 含叔丁醇体系的汽液平衡测定和关联[J]. 化学工程, 1995, 23(5): 11-14 |
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作者姓名: | 陈新志 陈钟秀 |
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摘 要: | 测定了正己烷─叔丁醇,正庚烷─叔丁醇体系的常压汽液平衡数据。采用马丁─侯状态方程、Wilson、NRTL活度系数模型关联了实验数据,计算值与实验值吻合较好。
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关 键 词: | 汽液平衡,正己烷─叔丁醇体系,正庚烷─叔丁醇体系,马丁─侯状态方程,Wilson方程,NRTL方程 |
Determination and correlation of vapor liquid equilibria for tertbutanol containing systems |
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Abstract: | apor liquid equilibrium data of n-hexane-tertbutanol and n-heptane-tertbutanol were measuredby using the modified Rose-Williams still and correlated with three thermodynamic models, Martin-Hou equation of state, Wilson and NRTL activity coefficient equations. Satisfactory results were ob-tained. |
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Keywords: | n-hexane/tertbutanol system n-heptane/tertbutanol system vapor-liquid equilibrium Mar-tin-Hou equation of state Wilson equation NRTL equation |
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