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Aluminophosphates Oxynitrides as Base Catalysts for the Production of Dicyanomethylene Derivative Dyes
Authors:M.J. Climent  A. Corma  R. Guil-Lopez  S. Iborra
Affiliation:(1) Instituto de Tecnología Química, (UPV-CSIC), Universidad Politécnica de Valencia, Avda. los Naranjos s/n, 46022 Valencia, Spain
Abstract:The two-step synthesis of dicyanomethylene derivative dyes has been performed using as base catalysts MgO, calcined hydrotalcites and ALPON. These solids catalyse with good conversions and selectivities the Knoevenagel reaction step, but only ALPON catalysts are able to catalyse efficiently the two reaction steps, as well as the global reaction in a ldquoone-potrdquo system.
Keywords:ALPON  base catalysts  dicyanomethylene derivative dyes  Knoevenagel  MgO  calcined hydrotalcites
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