Sintering characteristics of in situ formed low expansion ceramics from a powder precursor in the form of hydroxy hydrogel

Lithium aluminosilicate powder precursors of compositions Li₂O:Al₂O₃:SiO₂ as 1:1:2; 1:1:2.5 and 1:1:3 were prepared in the hydroxy hydrogel form by wet interaction technique in aqueous medium followed by sintering for ultimate synthesis of low expansion ceramics. Phases formed in the sintered specimens were analyzed by XRD technique. Thermal expansion of the specimens sintered at 1100, 1200 and 1300 °C were also measured. It was found that β-spodumene, lithium aluminum oxide and silica were the predominat phases in all the specimens. Sintering was optimum up to 1200 °C beyond which no further noticeable shrinkage was observed. The sintered specimens remained highly porous even after firing at 1300 °C, whose bulk density and apparent porosity were in the range of 1.25–1.42 g/cm³ and 43–48%, respectively. Thermal expansion characteristics and density of the sintered specimens were found to be primarily related to the composition of the phases formed during sintering. A porous low expansion ceramic monolith could be prepared using the present technique.