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Ti改性活性炭分离CH_4/N_2的实验研究
引用本文:马东祝,李坚,梁文俊,宁红艳,郭连杰,何洪.Ti改性活性炭分离CH_4/N_2的实验研究[J].北京工业大学学报,2013,39(5):780-784.
作者姓名:马东祝  李坚  梁文俊  宁红艳  郭连杰  何洪
作者单位:1. 北京工业大学环境与能源工程学院,北京100124;河北工业职业技术学院环境与化学工程系,石家庄050091
2. 北京工业大学环境与能源工程学院,北京,100124
基金项目:国家"863"计划资助项目
摘    要:针对甲烷气体(煤矿乏风瓦斯)的富集与分离,研究了活性炭吸附材料(AC)的Ti改性方法,讨论了对CH4/N2分离性能的影响.结果表明:Ti改性炭活性在1 100℃、N2保护焙烧后孔径分布更均一;CH4的吸附量达到34.4 mL/g,比未改性的活性炭和160℃水热方法 Ti改性的活性炭增加了51.5%;CH4常压穿透曲线的穿透点比未改性的活性炭和160℃水热方法 Ti改性的活性炭分别滞后了41%和50%.

关 键 词:Ti改性  CH4/N2分离  变压吸附(PSA)  常压穿透曲线

Experimental Study of Separating CH4/N2 by Using Ti Modified Activated Carbon
MA Dong-zhu,LI Jian,LIANG Wen-jun,NING Hong-yan,GUO Lian-jie,HE Hong.Experimental Study of Separating CH4/N2 by Using Ti Modified Activated Carbon[J].Journal of Beijing Polytechnic University,2013,39(5):780-784.
Authors:MA Dong-zhu  LI Jian  LIANG Wen-jun  NING Hong-yan  GUO Lian-jie  HE Hong
Affiliation:1(1.College of Environmetal and Energy Engineering,Beijing University of Technology,Beijing 100124,China; 2.Department of Environmental and Chemical Engineering,Hebei College of Industry and Technology, Shijiazhuang 050091,China)
Abstract:For methane(coal mine ventilation air methane) enrichment and separation,Ti modified method of activated carbon adsorption material(AC) was studied.The effect on separation performance of CH4/N2 was discussed.The results show that pore diameter distribution of Ti modified activated carbon after roasting at 1 100 ℃ and N2 protection is more uniform;CH4 adsorption quantity reaches 34.4 mL/g and increases 51.5% compared with unmodified activated carbon and Ti modified activated carbon at 160 ℃ hydrothermal method;CH4 breakthrough point of atmospheric breakthrough curve lags 41% and 50% respectively compared with unmodified activated carbon and Ti modified activated carbon at 160 ℃ hydrothermal method.
Keywords:Ti modification  CH4/N2 separation  pressure swing adsorption(PSA)  atmospheric breakthrough curve
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