Phase transition-induced high electromechanical activity in [(K0.5Na0.5)1−xLix](Nb0.8Ta0.2)O3 lead-free ceramic system |
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Authors: | Zuyong Feng Siu Wing Or |
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Affiliation: | aDepartment of Electrical Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, China |
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Abstract: | A high electromechanical activity is observed in the (K0.5Na0.5)1−xLix](Nb0.8Ta0.2)O3 (x = 0, 0.02, and 0.03) lead-free ceramic system at and around the orthorhombic (O)–tetragonal (T) phase transition temperature (TO–T). This activity is found to originate from an O–T phase transition region at ambient temperature rather than a classical morphotropic phase boundary (MPB) region intrinsic in the Pb(Zr1−xTix)O3 (PZT) lead-based ceramic system. Li modification enables a large decrease in TO–T instead of constituting a classical MPB. In contrast to the nearly temperature-independent classical MPB behavior in the PZT system, the strong temperature-dependent phase transition behavior in the system may impose a challenge to temperature demanding applications. |
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Keywords: | Electromechanical activity Lead-free ceramics Morphotropic phase boundary (MPB) Phase transition |
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