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Optical Property of Dy3+‐and Ce3+‐Doped Si–B–Na–Sr Glasses
Authors:Wanyi He  Xiangfu Wang  Jin Zheng  Xiaohong Yan
Affiliation:1. College of Electronic Science and Engineering, Nanjing University of Post and Telecommunications, , Nanjing, 210046 China;2. College of Science, Nanjing University of Aeronautics and Astronautics, , Nanjing, 211106 China
Abstract:Novel Dy3+ and Ce3+ doped Si–B–Na–Sr (SBNS) glasses were synthesized by melt‐quenching technique. Excited by 327 nm, the 0.5Dy3+‐and 0.5Ce3+‐doped SBNS exhibits white emission with Commission Internationale de L'Eclairage coordinates of (0.308, 0.280). Basic optical characterizations have been performed by measuring the absorption and emission spectra and calculating Judd–Ofelt intensity parameters, radiative probability, luminescence branching ratio, cross sections, and effective bandwidth. The Judd–Ofelt parameters Ω2, Ω4, and Ω6 indicate a high asymmetrical environment and covalent environment in the optical glass. The emission color of Ce3+ and Dy3+ codoped transparent glass can be tuned from blue to white through energy transfer from Ce3+ to Dy3+ ions. The resulting glass may have potential application in white‐light‐emitting source.
Keywords:
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