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Lattice and Grain‐Boundary Diffusion of Al in Tetragonal Yttria‐Stabilized Zirconia Polycrystalline Ceramics (3Y‐TZP) Analyzed Using SIMS
Authors:Kazimierz Kowalski  Katarzyna Obal  Zbigniew Pedzich  Krystyna Schneider  Mieczyslaw Rekas
Affiliation:1. Faculty of Metals Engineering and Industrial Computer Science, AGH University of Science and Technology, , Krakow, Poland;2. Faculty of Materials Science and Ceramics, AGH University of Science and Technology, , Krakow, Poland;3. Faculty of Computer Science, Electronics and Telecommunications, AGH University of Science and Technology, , Krakow, Poland
Abstract:Aluminum oxide was deposited on the surface of 3 mol% yttria‐stabilized tetragonal zirconia polycrystals (3Y‐TZP). The samples were annealed at temperatures from 1523 to 1773 K. Diffusion profiles of Al in the form of mean concentration vs. depth in B‐type kinetic region were investigated by secondary ion mass spectroscopy. The experimental results for the lattice diffusion (DB) and grain boundary diffusion (DGB) are as follows: urn:x-wiley:00027820:media:jace13126:jace13126-math-0001 and urn:x-wiley:00027820:media:jace13126:jace13126-math-0002 where δ is the grain‐boundary width and s is the segregation factor.
Keywords:
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