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降低烟气污染物三效助剂LTA-1的开发与应用
引用本文:齐文义,郝代军,袁强,刘淑芳.降低烟气污染物三效助剂LTA-1的开发与应用[J].炼油技术与工程,2009,39(7):58-61.
作者姓名:齐文义  郝代军  袁强  刘淑芳
作者单位:中国石化集团洛阳石油化工工程公司,河南省洛阳市,471003
摘    要:分析了催化裂化再生烟气中SOx,NOx和CO对环境、装置等的影响;介绍了LTA-1助剂的作用机理、助剂研制以及实验室评价结果;重点介绍了该助剂在中国石化济南分公司Ⅰ套催化裂化装置上的应用情况。结果表明,首先按催化剂藏量的2.5%将助剂加入装置,然后每天按催化剂单耗的2.5%补入助剂,可使再生烟气中的SOx质量浓度平均降低67.4%;在不停加原来使用的铂基助燃剂的基础上,可使再生烟气中的NOx质量浓度平均降低40.4%;并且对产品分布和产品性质没有不利影响。

关 键 词:催化裂化  再生烟气  三效助剂  脱除  SOx  NOx  CO

Development & commercial application of tri-functional additive LTA-1 for reducing FCC flue gas emission
Qi Wenyi,Hao Daijun,Yuan Qiang,Liu Shufang.Development & commercial application of tri-functional additive LTA-1 for reducing FCC flue gas emission[J].Petroleum Refinery Engineering,2009,39(7):58-61.
Authors:Qi Wenyi  Hao Daijun  Yuan Qiang  Liu Shufang
Affiliation:( SINOPEC Luoyang Petrochemical Engineering Corporation ( Luoyang 471003, Henan , China))
Abstract:The impacts of SOx, NOx and CO from regenerator flue gas on environment and FCC unit, etc are discussed. The working mechanism, preparation methods and laboratory results of LTA-1 additive, especially the results of commercial application in FCCU in SINOPEC Jinan Petrochemical Company are introduced. The results showed that when the first addition of additive was made at a dosage of 2.5% of catalyst inventory and followed by a make-up of 2.5 % of catalyst consumption each day, the SOx and NOx in flue gas were reduced by 67.4% and 40.4% respectively with addition of Pt-based combustion promoter. There is no negative impact on product qualities and product distribution.
Keywords:SOx  NOx  CO
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