| 缔合电解质溶液的积分方程理论 |
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| 引用本文： | 姜建文 刘洪来. 缔合电解质溶液的积分方程理论[J]. 化工学报, 1998, 49(2): 133-140 |
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| 作者姓名： | 姜建文 刘洪来 |
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| 作者单位： | 华东理工大学化学系!上海200237,华东理工大学化学系!上海200237,华东理工大学化学系!上海200237 |
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| 基金项目： | 国家自然科学基金!No.29736170，国家教委博土学科点专项科研基金!No.96025109 |
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| 摘 要： | 在粘性电解质模型（SEM）的基础上，研究了不等直径离子间有缔合作用的电解质溶液，其缔合位置小于或等于硬球的接触直径.求解Omstein-Zemike积分方程时，在核内和核外分别采用超网链近似（HNC）和平均球近似（MSA）作为封闭条件．系统的相关函数和热力学性质均表示为系统状态所决定的特性参数，并给出广泛的数值结果．
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| 关 键 词： | 电解质溶液 离子缔合 积分方程 缔合 SEM |
INTEGRAL EQUATION THEORY FOR ELECTROLYTE SOLUTION WITH IONS STICKINESS |
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| Jiang Jianwen,Liu Honglai,Hu Ying. INTEGRAL EQUATION THEORY FOR ELECTROLYTE SOLUTION WITH IONS STICKINESS[J]. Journal of Chemical Industry and Engineering(China), 1998, 49(2): 133-140 |
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| Authors: | Jiang Jianwen Liu Honglai Hu Ying |
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| Abstract: | Ornstein-Zernike（OZ）integral is solved for unsymmetrical sticky electrolyte solutions with overlap at various distances between ions equal to or less than the collision diameter.Based on the mean-spherical (MSA),all correlation functions and thermodynamic properties can be expressed explicitly in terms of the sticky parameters obtained through a self -consistent procedure.With the reference of an ideal-gas mixture,numerical results of osmotic coefficient and activity coefficient for mixtures with stickiness between oppositely charged ions are presented. |
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| Keywords: | electrolyte solution ion association integral equation correlation function excess properties |
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