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Effect of temperature on methyl radical generation over Sr/La2O3 catalysts
Authors:Mingting Xu  Jack H Lunsford
Affiliation:(1) Department of Chemistry, Texas A&M University, 77843 College Station, Texas, USA
Abstract:The role of gas phase CH3 radicals in the oxidative coupling of CH4 over 1 wt% Sr/La2O3 is supported by the observations that (i) this is a very effective catalyst for the generation of CH3 · radicals and (ii) the concentration of CH3 · radicals increases with temperature over the range of 450 °C–800 °C.
Keywords:Methane oxidation  methyl radicals  strontium/lanthanum oxide  temperature effects
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