Effect of gravity on crystallization in heavy metal fluoride glasses processed on the T-33 parabolic flight aircraft |
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Authors: | S Varma S E Prasad A Ahmad T A Wheat |
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Affiliation: | (1) Supan Technologies Inc., 1877 Chaine Court, Orleans, ON, Canada, K1C 2W6;(2) Sensor Technology Ltd., 20 Stewart Road, P.O. Box 97, Collingwood, ON, Canada, L9Y 3Z4;(3) MTL/CANMET, Natural Resources Canada, 405 Rochester St., Ottawa, ON, Canada, K1A 0G1 |
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Abstract: | Heavy metal fluoride (HMF) glasses are prone to micro-crystal formation and resulting optical degradation during their high-temperature processing for fibre drawing. It is believed that the absence of gravity-driven density segregation in microgravity can reduce this undesired micro-crystallization during the processing of HMF glasses. Experiments were conducted on the T-33 parabolic flight aircraft in microgravity and under 2-g acceleration to study the effect of gravity on crystallization in HMF glasses. These preliminary experiments indicated that gravity enhances crystallization in HMF glasses during their processing at 370–400°C. However, these results were not considered conclusive due to the short duration of 20 seconds available on the parabolic flight aircraft. Subsequent ground-based experiments were conducted on the T-33 payload using statistical design of experiments to simultaneously study the effect of glass composition, processing temperature, processing time and mode of heating (continuous or pulsed). These experiments indicated that a continuous processing time of over two minutes at crystallization temperatures is required to observe a statistically significant amount of crystallization in HMF glasses. This established the need for longer duration experiments on the sounding rocket, space shuttle or space station. |
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