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Polydopamine modified Au/FAU catalytic membrane for CO preferential oxidation
Authors:Li Peng  Limin Wang  Feng Zhu  Jinyun Liu  Wenfu Yan  Xuehong Gu
Affiliation:1.State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, 5 Xinmofan Road, Nanjing 210009, China;2.State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China
Abstract:A hollow-fiber-supported stable Au/FAU catalytic membrane was successfully synthesized through a polydopamine coating modification-removal strategy and used as a flow-through catalytic membrane reactor for preferential oxidation of CO. Small Au nanoparticles can be efficiently isolated by dopamine and the dopamine-derived carbon shells. The interactions between Au nanoparticles and zeolite layer support are enhanced during annealing at high temperature under an inert atmosphere. A zeolite membrane supported Au nanoparticle catalyst was obtained after the removal of carbon shells, which showed high catalytic activity and stability for the removal of CO from hydrogen.
Keywords:Zeolite membrane  CO oxidation  Gold catalyst  Surface modification  
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