| 3-(4-N-马来酰亚胺)苯基-2,4-二氢-1,3-苯并噁嗪的合成研究 |
| |
| 引用本文： | 陶果,杨刚.3-(4-N-马来酰亚胺)苯基-2,4-二氢-1,3-苯并噁嗪的合成研究[J].塑料工业,2011,39(6). |
| |
| 作者姓名： | 陶果 杨刚 |
| |
| 作者单位： | 1. 四川职业技术学院,四川遂宁,629000
2. 四川大学高分子科学与工程学院,四川成都,610065 |
| |
| 基金项目： | 四川省教育厅自然科学基金 |
| |
| 摘 要： | 以顺丁烯二酸酐、对硝基苯胺、甲醛、苯酚为原料,采用多步反应经中间产物N-(4-硝基苯基)马来酰亚胺(NPMI)、N-(4-氨基苯基)马来酰亚胺(APMI)、三嗪(TMIPT)等最终合成出一种新型的3-(4-N-马来酰亚胺)苯基-2,4-二氢-1,3-苯并噁嗪(MIPB),并采用1H NMR、FT-IR、EA等方法对产物MIPB进行了检测,证实了所得产物为目标物MIPB,并对其溶解性和合成条件进行了探讨.所得MIPB为金黄色疏松状固体,产品收率47%.
|
| 关 键 词： | 苯并噁嗪 合成 热固性 高性能聚合物 |
Study on Synthesis of 3-(4-N-Maleimido)Phenyl-2, 4-Dihydro-2H-1, 3-Benzoxazine |
| |
| TAO Guo,YANG Gang.Study on Synthesis of 3-(4-N-Maleimido)Phenyl-2, 4-Dihydro-2H-1, 3-Benzoxazine[J].China Plastics Industry,2011,39(6). |
| |
| Authors: | TAO Guo YANG Gang |
| |
| Affiliation: | TAO Guo1,YANG Gang2(1.Sichuan Vocational and Technical College,Suining 629000,China,2.College of Polymer Science & Engineering of Sichuan University,Chengdu 610065,China) |
| |
| Abstract: | The new MIPB was prepared from maleic anhydride,p-nitroaniline,paraformaldehyde and phenol by steps reactions.The N-(4-aminophenyl)maleimide,N-(4-aminophenyl)maleimide,TMIPT were the intermediate.The MIPB were confirmed by 1H-NMR,FT-IR and EA.The results confirmed that the production was the target object MIPB.Its solubility and synthesized conditions were discussed.The MIPB was a loosened golden-yellow solid;the yield of product was 47%. |
| |
| Keywords: | Benzoxazine Synthesis Thermoset High Performance Polymer |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
