Free radicals in coals and coal conversion. 2. Effect of liquefaction processing conditions on the formation and quenching of coal free radicals |
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Authors: | Leon Petrakis David W Grandy |
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Affiliation: | Gulf Research & Development Company, P.O. Drawer 2038, Pittsburgh, Pennsylvania 15230, USA |
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Abstract: | Free radicals are generally accepted as playing an important role in the liquefaction of coal. In a continuing series of studies, we are attempting to determine the relation between the nature and properties of free radicals and process variables such as residence time in a reactor, heating rates to achieve highest temperature and the role of various solvents and gases in stabilizing free radicals in lower-molecular-weight moieties. The free radical concentration after thermal treatments correlates well with the propensity of a given solvent to donate its hydrogen. |
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