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反应精馏隔壁塔内合成乙酸甲酯的模拟
引用本文:孙兰义,杨德连,李军,李青松.反应精馏隔壁塔内合成乙酸甲酯的模拟[J].化工进展,2009,28(1):19.
作者姓名:孙兰义  杨德连  李军  李青松
作者单位:中国石油大学(华东)化学化工学院
基金项目:教育部博士点基金新教师项目 
摘    要:提出了一种应用反应精馏隔壁塔合成乙酸甲酯的新工艺流程,采用反应精馏隔壁塔替代常规反应精馏流程中的反应精馏塔及甲醇回收塔。利用Aspen Plus模拟软件,对反应精馏隔壁塔及常规流程进行了模拟,比较分析了两种流程塔内液相组成分布,并分析了塔顶回流比与气相分配比对反应精馏隔壁塔的影响。结果显示新流程可以节能11.9%,并能降低设备投资费用和操作费用。

关 键 词:反应精馏隔壁塔  乙酸甲酯  合成  节能

Simulation of reactive distillation dividing wall column for synthesis of methyl acetate
SUN Lanyi,YANG Delian,LI Jun,LI Qingsong.Simulation of reactive distillation dividing wall column for synthesis of methyl acetate[J].Chemical Industry and Engineering Progress,2009,28(1):19.
Authors:SUN Lanyi  YANG Delian  LI Jun  LI Qingsong
Affiliation:School of Chemistry & Chemical Engineering, China University of Petroleum
Abstract:A novel single-column reactive distillation process was proposed for synthesis of methyl acetate,in which the reactive distillation dividing wall column was used instead of conventional reactive distillation column and methanol recovery column.Both the new process and conventional process were simulated with Aspen Plus.Liquid composition profiles of the two processes were compared.The influence of important parameters,such as the reflux ratio and vapor distribution ratio,on the performance of the novel proc...
Keywords:reactive distillation dividing wall column  methyl acetate  synthesis  energy saving  
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