| 无皂苯丙乳液的合成及性能研究 |
| |
| 引用本文： | 陈晓锋,高彦芳,刘德山. 无皂苯丙乳液的合成及性能研究[J]. 高分子材料科学与工程, 2004, 20(2): 54-56 |
| |
| 作者姓名： | 陈晓锋 高彦芳 刘德山 |
| |
| 作者单位： | 清华大学化工系和材料科学与工程研究院,北京,100084;清华大学化工系和材料科学与工程研究院,北京,100084;清华大学化工系和材料科学与工程研究院,北京,100084 |
| |
| 摘 要： | 在少量甲基丙烯酸钠盐的存在下，成功合成了具有高稳定性、高透明性的聚(苯乙烯／丙烯酸丁酯)P(St／BA)无皂共聚乳液。同时．本文还对不同配方的乳液及其涂膜的综合性能进行了研究，总结了组成与性能之间的对应关系。其中，着重讨论了单体组成与乳液表面能、乳胶粒尺寸之间的关系。结果表明，随单体配比中St含量的增加。乳液接触角和乳胶粒粒径减小。乳胶粒具有均一的尺寸，并显示出明显的核壳结构。本文通过对苯丙无皂乳液组成与性能关系的研究，积累了一定量的理论数据，为无皂乳液产品的进一步开发提供了条件。
|
| 关 键 词： | 甲基丙烯酸钠盐 苯丙乳液 无皂乳液聚合 |
| 文章编号： | 1000-7555(2004)02-0054-03 |
| 修稿时间： | 2002-03-26 |
SYNTHESIS AND PROPERTIES OF St/BA SOAP-FREE EMULSION |
| |
| CHEN Xiao-feng,GAO Yan-fang,Liu De-shan. SYNTHESIS AND PROPERTIES OF St/BA SOAP-FREE EMULSION[J]. Polymer Materials Science & Engineering, 2004, 20(2): 54-56 |
| |
| Authors: | CHEN Xiao-feng GAO Yan-fang Liu De-shan |
| |
| Abstract: | A soap-free poly(styrene/butylacrylate) P (St/BA) emulsion was prepared in the presence of the sodium salt of methacrylic acid. The influence of monomer component on the synthesis and properties of the elmulsion and its coating were studied. Especially, the influence on surface tension and particle diameter of emulsion were studied mainly. The contact angle and the particle diameter of P(St/BA)emulsion was decreased with the amount of St increasing. The emulsion is very stable and its coating shows excellent transparency. |
| |
| Keywords: | sodium salt of methacrylic acid St/BA emulsion soap-free emulsion polymerization |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
