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Creep behavior of eutectic Sn-Cu lead-free solder alloy
Authors:C M L Wu  M L Huang
Affiliation:(1) Department of Physics and Materials Science, City University of Hong Kong, Hong Kong SAR, People’s Republic of China;(2) Department of Materials Engineering, Dalian University of Technology, 116024 Dalian, People’s Republic of China
Abstract:Tensile creep behavior of precipitation-strengthened, tin-based eutectic Sn-0.7Cu alloy was investigated at three temperatures ranging from 303–393 K. The steady-state creep rates cover six orders of magnitude (10−3−10−8 s−1) under the stress range of σ/E=10−4−10−3. The initial microstructure reveals that the intermetallic compound Cu6Sn5 is finely dispersed in the matrix of β-Sn. By incorporating a threshold stress, σ th, into the analysis, the creep data of eutectic Sn-Cu at all temperatures can be fitted by a single straight line with a slope of 7 after normalizing the steady-state creep rate and the effective stress, indicating that the creep rates are controlled by the dislocation-pipe diffusion in the tin matrix. So the steady-state creep rate, 
$$\dot \varepsilon $$
, can be expressed as 
$$\dot \varepsilon  = {\rm A}\frac{{Gb}}{{RT}}\left( {\frac{{\sigma th}}{G}} \right)^7 $$
exp 
$$\left( {\frac{{Q_C }}{{RT}}} \right)$$
, where Qc is the activation energy for creep, G is the temperature-dependent shear modulus, b is the Burgers vector, R is the universal gas constant, T is the temperature, σ is the applied stress, A is a material-dependent constant, and 
$$\sigma _{th}  = \sigma _{OB} \sqrt {1 - k_R^2 } $$
, in which σ OB is the Orowan bowing stress, and kR is the relaxation factor. An erratum to this article is available at .
Keywords:Creep  eutectic Sn-Cu  lead-free solder alloy  precipitation strengthening  activation energy
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