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Thermal, Optical, and Electrical Properties of Gel Grown ZMTC
Authors:K Ambujam  S Selvakumar  Ginson P Joseph  I Vetha Potheher  P Sagayaraj
Affiliation:  a Department of Physics, Queen Mary's College, Chennai, India b Department of Physics, Loyola College, Chennai, India
Abstract:The bimetallic thiocyanate of the group IIB divalent d10 ions Zn2+ and Hg2+ having unique characteristics: The pale color and high thermal stability—Zinc Mercury tetrathiocyanate (ZMTC) is chosen for growth and study. ZMTC is grown in silica gel by chemical reaction method and characterized by single crystal XRD, FTIR, FT-Raman, UV-Vis-NIR, NLO, TGA/DTG, DSC, AC conductivity, and dielectric studies. It has wide transparency window and possesses high second harmonic generation efficiency. Its thermal stability is very high. The dielectric permittivity of this material is very low.
Keywords:AC conductivity  Dielectric behaviour  FTIR  FT-Raman  Gel growth  NLO  Optical absorbance  Single crystal XRD  Thermal stability
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