| 以固载杂多酸(盐)为催化剂合成对羟基苯甲酸甲酯 |
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| 引用本文： | 郭虹,王丹,孔祥文,苏杰.以固载杂多酸(盐)为催化剂合成对羟基苯甲酸甲酯[J].沈阳化工学院学报,2005,19(1):8-10. |
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| 作者姓名： | 郭虹 王丹 孔祥文 苏杰 |
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| 作者单位： | 沈阳化工学院,辽宁,沈阳,110142 |
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| 基金项目： | 沈阳化工学院中青年科研启动基金资助项目(200013) |
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| 摘 要： | 以对羟基苯甲酸和甲醇为原料合成对羟基苯甲酸甲酯的催化剂及反应条件进行研究．考察催化剂用量、反应时间、醇酸比等对合成产物的影响，给出适宜的酯化工艺条件，此时对羟基苯甲酸酯合成反应的酯化率为84．6％，实验表明，固载杂多酸(盐)TiSiW12O40／TiO2是合成对羟基苯甲酸甲酯的良好催化剂。目标产物经熔点测定和红外光谱检测，其熔点和文献值相吻合，红外谱图与相应的标准谱图一致．
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| 关 键 词： | 对羟基苯甲酸甲酯（尼泊金甲酯） 催化剂 杂多酸（盐） 酯化反应 |
| 文章编号： | 1004-4639(2005)01-0008-03 |
Catalytic Synthesis of Methyl p-Hydroxyl Benzoate by Heteropoly Acid (Salts) |
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| GUO Hong,WANG Dan,KONG Xiang-wen,SU Jie.Catalytic Synthesis of Methyl p-Hydroxyl Benzoate by Heteropoly Acid (Salts)[J].Journal of Shenyang Institute of Chemical Technolgy,2005,19(1):8-10. |
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| Authors: | GUO Hong WANG Dan KONG Xiang-wen SU Jie |
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| Abstract: | The heteropoly acid (salts) was used as catalyst for the synthesis of methyl p-hydroxyl benzoate, which is a food preservative. The optimum experimental conditions were obtained. Effects of the amount of the catalyst, the reaction time and the ratio of reactants were investigated. Under the condition, the yield of methyl p-hydroxyl benzoate could reach 84.6 %. The melting point tested in this study agrees to literature value, and its IR spectrum is consistent with the standard. |
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| Keywords: | methyl p-hydroxyl benzoate catalyst heteropoly acid esterification |
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