Ultrasound velocity and adiabatic compressibility of GdCl3-MCl (M = Na,Cs) melts |
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Authors: | V. I. Minchenko V. A. Khokhlov I. V. Korzun |
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Affiliation: | 1.Institute of High-Temperature Electrochemistry, Ural Branch,Russian Academy of Sciences,Yekaterinburg,Russia |
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Abstract: | The ultrasound velocity in GdCl3 + MCl (M = Na, Cs) chloride melts is measured over wide temperature and composition ranges, and their adiabatic compressibility is calculated. A correlation is established between the relative deviations of these properties from their values in hypothetic ideal salt mixtures and the reciprocal alkali-metal cation radii. The role of lanthanide compression in the propagation of sound vibrations in the chlorides of cerium group REMs is revealed. |
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