Synthesis, Crystal Structure and Electrochemical Properties of 2D Network Complex {[K(N18C6)]2(CH3CN)}[Ni(mnt)2] with N18C6 = 2,3-Naphtho-18-Crown-6 |
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Authors: | Xi-Ke Gao Jian-Min Dou Feng-Ying Dong Da-Cheng Li Da-Qi Wang |
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Affiliation: | 1. Department of Chemistry, Liaocheng University, P. R. China
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Abstract: | A novel 2D network complex [K(N18C6)]2(CH3CN) [Ni(mnt)2] (1) (where N18C6 = 2,3-naphtho-18-crown-6 and mnt = maleonitriledithiolate) has been synthesized and characterized by elemental analysis, FT-IR spectrum, UV-visible spectrum and single crystal X-ray diffraction. The complex molecules are linked into 1D chains by the bridging CH3CN molecules through weak K-N interactions and the result chains are assembled into a novel 2D network through the inter-chain π–π stacking interactions occurred between adjacent naphthylene moieties of N18C6. The cyclic voltammogram of the title complex displays a reversible process corresponding to the [Ni(mnt)2]?/[Ni(mnt)2]2? reaction. |
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