Density and electrical conductivity of molten NaCl-KCl-AlCl3 mixtures |
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Authors: | K. Matias̆ovský P. Fellner M. Chrenková-Pauc̆írová G. Bräutigam H.-H. Emons |
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Affiliation: | Institute of Inorganic Chemistry, Slovak Academy of Sciences, 809 34 Bratislava, Czechoslovakia;Department of Chemistry, Technical University “Carl Schorlemmer”, 42 Merseburg, German Democratic Republic Czechoslovakia;Department of Chemistry, Academy of Mining of Freiberg, 92 Freiberg (Sachs), German Democratic Republic Czechoslovakia |
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Abstract: | The density and specific electrical conductivity were investigated for molten ternary NaCl-KCl-AlCl3 mixtures of interest to new industrial processes for electrolytic aluminium deposition. A method for the calculation of density and electrical conductivity of molten ternary mixtures on the basis of experimentally determined values for the binary systems NaCl-AlCl3, NaCl-KCl and KCl-AlCl3 has been proposed. The difference between the experimental and calculated density and electrical conductivity values of the ternary system was less than ± 1.5% for the density and ± 5% for the electrical conductivity, respectively. |
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