Conductometric studies on the dissociation constants of phosphoric acid in methanol-water mixtures |
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| Authors: | A Bhattacharyya AK Maandal SC Lahiri |
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| Affiliation: | Department of Chemistry, University of Kalyani, Kalyani 741235, India |
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| Abstract: | The dissociation constants of phosphoric acid have been determined in methanol-water mixtures (8.0–87% by weight of methanol) by the method suggested by Gelb. The results have been verified by Fuoss—Kraus method. Δ0 values of HClO4, KClO4 and KH2PO4 (and hence of H3PO4) in mixed solvents have been determined in the usual way. The role of solvents on the dissociation constants has been discussed. |
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