|
|||||
|
|
Iridium‐Catalyzed Enantioselective Hydrogenation of Cyclic Imines |
|
| Authors: | Mingxin Chang Wei Li Guohua Hou Xumu Zhang |
| Abstract: | A catalytic complex made from Ir(COD)Cl]2 di‐μ‐chloro‐bis(1,5‐cyclooctadiene)diiridium(I)] precursor and (S,S)‐f‐Binaphane ((R,R)‐1,1′‐bis{(R)‐4,5‐dihydro‐3H‐dinaphtho1,2‐c:2′,1′‐e]phosphepino}ferrocene) ligand effectively catalyzed the enantioselective hydrogenation of cyclic imines with high reactivity and good enantioselectivity. |
| Keywords: | asymmetric catalysis cyclic imines enantioselectivity hydrogenation iridium |