Chemistry of Modified Fenton’s Reagent (Catalyzed H2O2 Propagations–CHP) for In Situ Soil and Groundwater Remediation

The use of modified Fenton’s reagent, or catalyzed H2O2 propagations (CHP), has become increasingly popular for the in situ and ex situ treatment of surface soils and the in situ remediation of the subsurface. The process is based on the catalyzed decomposition of hydrogen peroxide by soluble iron, iron chelates, or iron minerals to generate the strong oxidant hydroxyl radical as well as other reactive oxygen species. Some of these species function as reductants and nucleophiles and may be responsible for the enhanced treatment of sorbed and nonaqueous phase liquid (NAPL) contaminants that is sometimes observed in the field. This paper serves as a review of the process chemistry of CHP; the goal is to provide researchers and practitioners with fundamental concepts that will aid in applying the CHP process to soil and groundwater contamination. Although the importance of well placement and the method of reagent injection must be considered in CHP remediation, understanding and promoting the most effective process chemistry is essential to successful soil and groundwater remediation.