| 新型邻苯二甲腈基醚化新酚树脂的制备与性能 |
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| 引用本文： | 罗振华,张勃兴,周恒,冀志宏,韩伟健,赵彤.新型邻苯二甲腈基醚化新酚树脂的制备与性能[J].材料开发与应用,2011,26(2):51-55. |
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| 作者姓名： | 罗振华 张勃兴 周恒 冀志宏 韩伟健 赵彤 |
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| 作者单位： | 1. 中国科学院化学研究所,北京,100080
2. 中国科学院化学研究所,北京,100080;中国科学院研究生院,北京,100039 |
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| 摘 要： | 以碱为催化剂,通过新酚树脂与4-硝基邻苯二甲腈之间的亲核取代反应,制备了邻苯二甲腈醚化新酚树脂(BPX)。流变性能测试结果表明,BPX树脂在165~285℃间黏度值小于400mPa.s,表明该树脂具有优良的加工性能。DSC测试结果表明,BPX树脂的固化温度范围为320~420℃,固化反应峰值温度为386.24℃,固化放热约为182.26 J/g。该树脂的固化物表现出优良的耐热性,其储能模量起始下降温度高于450℃,5%失重温度(T5d)约为519℃,氮气氛围900℃残碳率约为75%。
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| 关 键 词： | 邻苯二甲腈 新酚树脂 加成固化 工艺性 耐热性 |
Preparation and Properties of Bisphthalonitrie-etherified Xylok Resin |
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| LUO Zhen-hua,ZHANG Bo-xing,ZHOU Heng,JI Zhi-hong,HAN Wei-jian,ZHAO Tong.Preparation and Properties of Bisphthalonitrie-etherified Xylok Resin[J].Development and Application of Materials,2011,26(2):51-55. |
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| Authors: | LUO Zhen-hua ZHANG Bo-xing ZHOU Heng JI Zhi-hong HAN Wei-jian ZHAO Tong |
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| Affiliation: | 1(1.Institute of Chemistry,the Chinese Academy of Sciences,Beijing 100080 China;2.Graduate School of the Chinese Academy of Sciences,Beijing 100039 China) |
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| Abstract: | Bisphthalonitrile-etherified xylok resin(BPX) was synthesized through nucleophilic replacing reaction between 4-nitro bisphthalonitirle and xylok resin with base as catalyst.The results of rheology test showed that the viscosity of BPX resin was below 400 MPa.s at 165~285℃,indicating that the resin possesses excellent processing capability.DSC curve of BPX resin revealed that the thermal polymerization reaction occurred at 320～420℃with peak temperature of 386.24℃ and exothermic enthalpy of 182.26J/g.BPX resin exhibited excellent thermal stability.The results of TGA showed that 5% weight loss temperature and char yield at 900℃ were about 519℃ and 75% respectively. |
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| Keywords: | Bisphthalonitrile xylok resin Addition-curable Processing capability Thermal stability |
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