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Enhancing near-infrared solar cell response using upconverting transparentceramics
Authors:M. Liu  Yalin LuZ.B. Xie  G.M. Chow
Affiliation:a Department of Materials Science and Engineering, University of Science and Technology of China, 96 Jinzhai Road, Hefei City 230026, PR China
b Department of Materials Science and Engineering, National University of Singapore, Kent Ridge, Singapore 117574, Singapore
Abstract:In order to demonstrate efficiency improvement of solar cells through utilization of frequency-shifted sub-band-gap photons, we prepared Y3Al5O12 transparent ceramics co-doped with 3.0 at% Yb3+ and 0.5 at% Er3+ (YAG:3.0Yb/0.5Er) by solid state reaction. The material’s upconversion luminescence was investigated and it was found that near-infrared light could be effectively converted to green light centered at 563 nm, where a dye-sensitized solar cell normally possessed high spectral response. Using a thin disk of YAG:3.0Yb/0.5Er transparent ceramics attached to the rear of the dye-sensitized solar cell, the near-infrared response of the dye-sensitized solar cell was enhanced, due to the frequency upconversion.
Keywords:Rare earth   YAG   Dye-sensitized solar cells   Spectral response
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