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Basic examination of membrane electrode assembly of proton exchange membrane fuel cell considering heat deterioration
Authors:Daisuke Tashima  Yujiro SakaguchiHiroaki Hidaka  Masahisa Otsubo
Affiliation:a Interdisciplinary Research Organization, University of Miyazaki, 1-1 Gakuenkibanadai-Nishi 1-1, Miyazaki 889-2192, Japan
b Department of Electrical and Electronic Engineering, Graduate School of Engineering, University of Miyazaki, 1-1, Gakuen Kibana-dai Nishi, Miyazaki 889-2192, Japan
c Department of Electrical and Electronic Engineering, Faculty of Engineering, University of Miyazaki, 1-1, Gakuen Kibana-dai Nishi, Miyazaki 889-2192, Japan
Abstract:The purpose of this research is to develop a standard preparation method for membrane electrode assemblies (MEAs). Therefore, the preparation method for multilayered MEAs with gas diffusion layers (GDLs) and the degree to which polymer membranes deteriorate by heating were studied. As a result, improvement of power density by making multi catalyst layers provides a solution to some problems found in thin polymer membranes. In addition, it was found that improving the diffusion of gas through two-layer GDLs in cathode (duct side: carbon paper, catalyst layer side: carbon cross) results in a cross leak reduction. Moreover, a making condition of MEAs was optimized by varying the temperatures used for the multi catalyst layers and two-layer GDLs. The analysis of heat deterioration of the Nafion membrane using X-ray photoelectron spectroscopy (XPS) indicates that the optimal hot press temperature is 130 °C.
Keywords:Proton exchange membrane fuel cell   Membrane electrode assemblies   Catalyst   Multilayered
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