| 萃取光度法测定钼精矿浸出液中的铼含量 |
| |
| 引用本文： | 王毅梦,樊雪梅,屈佳,牟小卫. 萃取光度法测定钼精矿浸出液中的铼含量[J]. 分析仪器, 2017, 0(3). DOI: 10.3936/j.issn.1001-232x.2017.03.012 |
| |
| 作者姓名： | 王毅梦 樊雪梅 屈佳 牟小卫 |
| |
| 作者单位： | 1. 商洛学院化学工程与现代材料学院,商洛,726000;2. 陕西炼石矿业有限公司,西安,710062 |
| |
| 基金项目： | 陕西省科技统筹创新工程计划项目，陕西省教育厅项目，陕西省尾矿资源综合利用重点实验室项目，商南县科技局计划项目 |
| |
| 摘 要： | 使用萃取光度法对钼精矿浸出液中的铼进行测定,对萃取、显色及测定过程进行了试验,优化了掩蔽剂用量、萃取次数、萃取时间、pH、水浴温度及还原剂用量等条件。结果表明:在波长426nm处,铼在2~30μg/mL浓度范围内与其吸光度呈良好的线性关系,RSD小于2.3%,检出限(3s/k)为0.08μg/mL,回收率在91.2%~103.4.8%之间,与ICP-AES标准加入法进行对比,结果一致。
|
| 关 键 词： | 浸出液 硫氰酸钾 铼 |
Determination of rhenium in the leaching solution of molybdenum ores by extraction-spectrophotometry |
| |
| Wang Yimeng,Fan Xuemei,Qu Jia,Mou Xiaowei. Determination of rhenium in the leaching solution of molybdenum ores by extraction-spectrophotometry[J]. Analytical Instrumentation, 2017, 0(3). DOI: 10.3936/j.issn.1001-232x.2017.03.012 |
| |
| Authors: | Wang Yimeng Fan Xuemei Qu Jia Mou Xiaowei |
| |
| Abstract: | The extraction-spectrophotometric method was used to determine the rhenium in leaching solution of molybdenum ores. In the method, the extraction and deternination procedures were investigated and the experimental conditions were studied systematically. The results indicated that the linear regression equation of the method was A =0.01114C + 0.0229, the correlation coefficition was 0.9992, the precision (RSD%) was less than 2.3% and the recoveries were between 91.2% and 103.4%. The determination results were consistent with that of ICP method. |
| |
| Keywords: | leaching solution potassium thiocyanate rhenium |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
|
