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Effects of Two-stage Heat Treatment on Delayed Coke and Study of Their Surface Texture Characteristics
Authors:Ui-Su Im  Jiyoung Kim  Seon Ho Lee  Byung-Rok Lee  Dong-Hyun Peck  Doo-Hwan Jung
Affiliation:1.Advanced Energy Technology,University of Science and Technology,Daejeon,Republic of Korea;2.New and Renewable Energy Research Division,Korea Institute of Energy Research,Daejeon,Republic of Korea;3.Department of Chemical and Biomolecular Engineering,Yonsei University,Seoul,Republic of Korea
Abstract:In the present study, surface texture features and chemical properties of two types of cokes, made from coal tar by either 1-stage heat treatment or 2-stage heat treatment, were researched. The relationship between surface texture characteristics and the chemical properties was identified through molecular weight distribution, insolubility of coal tar, weight loss with temperature increase, coking yield, and polarized light microscope analysis. Rapidly cleared anisotropy texture in cokes was observed in accordance with the coking temperature rise. Quinoline insolubility and toluene insolubility of coal tar increased with a corresponding increases in coking temperature. In particular, the cokes produced by the 2-stage heat treatment (2S-C) showed surface structure of needle cokes at a temperature approximately 50°C lower than the 1-stage heat treatment (1S-C). Additionally, the coking yield of 2S-C increased by approximately 14% in comparison with 1S-C.
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