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Lanthanzirkonat: ein innovatives Wärmedämmschichtmaterial. Lanthanum zirconate: an innovative Thermal Barrier Material
Authors:Erich Lugscheider  Kirsten Bobzin  Kristijan Lackner
Abstract:This paper presents the work of the research project AiF‐13114 N/1. Within the scope of this project coating systems from Lanthanum Zirconate and Y ttria s tabilised Z irconia (YSZ) were developed by use of E lectron B eam P hysical V apour D eposition (EB‐PVD). In addition, the potentials of Lanthanum Zirconate and YSZ as thermal barrier coatings within gas turbines were examined. Basis of the coating development was the use of powdery Lanthanum and YSZ, that were vaporised in a PVD‐machine from a double‐grooved cupreous crucible. Process parameters are evaluated to gain long lasting, columnar Lanthanum Zirconate EB‐PVD coatings with high stability, low heat conductivity a higher sintering inertness, that offer the opportunity to increase the temperature within the first stage of a gas turbine system 1, 2, 3, 4, 5, 6]. Therefor YSZ ‐ commonly used as conventional thermal barrier coating ‐ was used as a reference system during the tests. As base material Inconel Alloy 600 (a nickel‐based superalloy) was applied. The microstructure and the topography of the developed coating systems were characterized with the help of scanning electron microscopy. Nanoindentation proved to be a measurement method in order to define the stiffness distribution along the columns. The thermal cycle durability was determined via thermal cycle test.
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