Assessment of B4C reaction with liquid iron alloys |
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Authors: | B S Terry O S Chinyamakobvu |
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Affiliation: | (1) Department of Materials, Imperial College, SW7 2BP London, UK;(2) Present address: Department of Metallurgical Engineering, University of Zimbabwe, Harare, Zimbabwe |
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Abstract: | The degree of reaction achieved when B4C powders are brought into contact with liquid iron alloys has been assessed by a levitation dispersion test. Reaction occurs rapidly, leading to boron carbide dissolution and iron boride formation. In carbon-free iron alloys borocarbide, Fe23(C, B)6, also forms and in low-carbon iron alloys free graphite was also formed. Highcarbon alloys reacted to form both Fe3(C, B) and free graphite. Attempts to provide protection for the B4C by forming a TiC coating on its surface byin situ reactions with liquid Fe-Ti and Fe-Ti-C alloys proved unsuccessful, with TiC forming as a dispersed phase throughout the iron matrix |
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