Crosslinked poly(vinyl alcohol)/carboxymethyl chitosan hydrogels for removal of metal ions and dyestuff from aqueous solutions |
| |
| Authors: | Magdy W. Sabaa Riham R. Mohamed S. H. Eltaweel Rania S. Seoudi |
| |
| Affiliation: | 1. Chemistry Department, Faculty of Science, Cairo University, Giza, Egypt;2. Materials Science and Engineering Department, Faculty of Engineering and Materials Science, German University in Cairo on leave of Chemistry Department, Faculty of Science, Cairo University |
| |
| Abstract: | Hydrogels composed of poly(vinyl alcohol) (PVA) and carboxymethyl chitosan (CMCh) were synthesized via ultraviolet (UV) irradiation that can be used in several industrial fields. Several analysis tools were used to characterize the physical and thermal properties of CMCh/PVA hydrogels namely FT‐IR, scanning electron microscope (SEM), XRD, thermogravimetric analysis (TGA), and differential scanning calorimetery (DSC). TGA results showed that CMCh/PVA hydrogels are thermally more stable than CMCh and their thermal stability increases as PVA content increases in the hydrogel. Also, DSC results showed that CMCh/PVA hydrogels are at least partial miscible blends. Moreover, the swelling behavior of the CMCh/PVA hydrogels was studied in different buffered solutions and in different salt solutions at various concentrations. CMCh/PVA hydrogels swell much more than CMCh especially at alkaline pH. Both metal and dye uptake were studied for CMCh/PVA hydrogels. The hydrogels adsorb much more dyestuff and metal ions like Cu2+, Cd2+, and Co2+ than CMCh itself. Much dyestuff and metal ions are adsorbed by the hydrogels as PVA content increases in the hydrogel. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 |
| |
| Keywords: | hydrogels swelling metal uptake dye uptake thermal analysis physical analysis |
|
|
