|
|||||
|
|
| 富氮化合物5,5′-联四唑-1,1′-二氧二羟铵的合成工艺 | |
| 引用本文： | 王小军,苏强,张晓鹏,王俊峰,张春源,王霞,尚凤琴,金韶华. 富氮化合物5,5′-联四唑-1,1′-二氧二羟铵的合成工艺[J]. 含能材料, 2015, 23(5): 424-427 |
| 作者姓名： | 王小军 苏强 张晓鹏 王俊峰 张春源 王霞 尚凤琴 金韶华 |
| 作者单位： | 1. 甘肃银光化学工业集团有限公司,甘肃白银730900;北京理工大学材料科学与工程学院,北京100081 2. 甘肃银光化学工业集团有限公司,甘肃白银,730900 3. 北京理工大学材料科学与工程学院,北京,100081 |
| 摘 要： | 以40％乙二醛水溶液和盐酸羟胺为原料,通过取代、氯化、叠氮化、成环、成盐反应制备了5,5'-联四唑-1,1'-二氧二羟铵(TKX-50).采用元素分析,核磁对其结构进行表征,并进行了撞击感度和摩擦感度测试.研究了反应温度、保温时间、保温温度对关键中间体5,5'-联四唑-1,1'-二羟基二水合物(BTO)收率影响,以及羟胺水溶液浓度对TKX-50收率影响.结果表明,TKX-50的撞击感度H50为41 cm,摩擦感度爆炸百分数为0％.羟胺水溶液较佳浓度为50％,成环的较佳反应条件为:反应温度0～5℃,保温时间12h,保温温度20～25℃. |
| 关 键 词： | 含能材料 5,5'-联四唑-1,1'-二氧二羟铵(TKX-50) 合成 感度 |
| 收稿时间： | 2014-01-07 |
| 修稿时间： | 2014-09-22 |
Synthesis of Dihydroxylammonium 5,5'-Bistetrazole-1,1 '-diolate |
|
| WANG Xiao-jun,SU Qiang,ZHANG Xiao-peng,WANG Jun-feng,ZHANG Chun-yuan,WANG Xi,SHANG Fen-qin and JIN Shao-hua. Synthesis of Dihydroxylammonium 5,5'-Bistetrazole-1,1 '-diolate[J]. Chinese Journal of Energetic Materials, 2015, 23(5): 424-427 | |
| Authors: | WANG Xiao-jun SU Qiang ZHANG Xiao-peng WANG Jun-feng ZHANG Chun-yuan WANG Xi SHANG Fen-qin JIN Shao-hua |
| Affiliation: | Research Institute of Gan Su Ying Guang Chemical Industry Group, Baiyin 730900, China ;School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China,Research Institute of Gan Su Ying Guang Chemical Industry Group, Baiyin 730900, China ;School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China,Research Institute of Gan Su Ying Guang Chemical Industry Group, Baiyin 730900, China,School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China,School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China,Research Institute of Gan Su Ying Guang Chemical Industry Group, Baiyin 730900, China,Research Institute of Gan Su Ying Guang Chemical Industry Group, Baiyin 730900, China and School of Material Science and Engineering, Beijing Institute of Technology, Beijing 100081, China |
| Abstract: | |
| Keywords: | energetic materials dihydroxylammonium 5,5'-bistetrazole-1,1 '-diolate(TKX-50) synthesis sensitivity |
| 本文献已被 万方数据 等数据库收录！ | |
| 点击此处可从《含能材料》浏览原始摘要信息 | |
| 点击此处可从《含能材料》下载全文 | |