Abstract: | As a common flux agent, B2O3–CuO was introduced into Li2TiO3 system to reduce the sintering temperature for the requirements of LTCC applications. The optimal mass ratio of CuO to B2O3 was innovatively explored. When the mass ratio of CuO to B2O3 increased to 1.2:1.0, excellent microwave dielectric properties were obtained in LTMF<ZN0.892+CB1.2 ceramic of εr = 13.23, Q × f = 62,749 GHz, τf = -2.48 ppm/°C and the sintering temperature was reduced from 1300 to 930 °C. In a wide temperature range, the sample still maintain high temperature stability of |τf| < 5 ppm/°C (-40–120 °C). Based on the LTMF<ZN0.892+CB1.2 substrate, a millimeter wave microstrip antenna resonated at 30.12 GHz was designed with a considerably high radiation efficiency of 93.94% and a signal gain of 4.87 dB. Comprehensive microwave dielectric properties make LTMF<ZN0.892+CB1.2 become a candidate material for LTCC applications. |