| O,O|二乙基硫代磷酰氯高温合成工艺 |
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| 引用本文： | 朱怀锐,李雪辉,王璐. O,O|二乙基硫代磷酰氯高温合成工艺[J]. 武汉工程大学学报, 2012, 0(2): 38-40 |
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| 作者姓名： | 朱怀锐 李雪辉 王璐 |
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| 作者单位： | 湖北省蕲农化工有限公司， 湖北 蕲春 435315 |
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| 摘 要： | 研究了一种合成高质量O,O|二乙基硫代磷酰氯的新方法.该方法以五硫化二磷为起始原料，经过酯化、氯化和水解制成O,O|二乙基硫代磷酰氯.研究结果表明:反应总收率905%，含量992%，该工艺为对环境友好的绿色化学工艺.
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| 关 键 词： | O O|二乙基硫代磷酰氯 高温 五硫化二磷 硫化钠 精制 |
High temperature synthesis process of O,O|Diethyl dithiophosphate phosphoryl chloride |
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| ZHU Huai|rui,LI Xue|hui,WANG Lu. High temperature synthesis process of O,O|Diethyl dithiophosphate phosphoryl chloride[J]. Journal of Wuhan Institute of Chemical Technology, 2012, 0(2): 38-40 |
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| Authors: | ZHU Huai|rui LI Xue|hui WANG Lu |
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| Affiliation: | Hubei Qinong chemical CoLtd, Qichun 435315,China |
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| Abstract: | A high temperature synthetic method for obtaining high|quality O,O|diethyl dithiophosphate phosphoryl chloride was presentedWith five phosphorus sulfide as starting materials, O,O|diethyl phosphorothioate phosphoryl chloride was made after hydrolysis of esters, chlorinatedThe total yield reaches 905% and the content is more than 992%The process is a green chemical technology being more friendly to the environment
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| Keywords: | O O|Diethyl dithiophosphate phosphoryl chloride high temperature five phosphorus sulfide sodium sulfide refined |
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