Catalytic combustion of benzene over supported metal oxides catalysts |
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Authors: | Email author" target="_blank">Seong-Soo?HongEmail author Gwang-Ho?Lee Gun-Dae?Lee |
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Affiliation: | (1) Division of Chemical Engineering, Pukyong National University, 100 Yongdang-dong, Nam-ku, 608-739 Busan, Korea |
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Abstract: | Catalytic combustion of benzene over supported metal oxides has been investigated. The catalysts have been prepared by incipient
wetness method and characterized by XRD, FT-Raman, ESR and TPR. Among supported metal oxides, CuOx, supported on TiO2 is found to have the highest activity for benzene oxidation. In addition, among the catalysts of copper oxide supported on
TiO2, A12O3 and SiO2, titania-supported catalyst (CuOx/TiO2) gives the highest catalytic activity. CuOx/TiO2 (Cu loading 5.5 wt%) shows the total oxidation of benzene at about 250 °C. From the ESR and FT-Raman results, the CuO dispersed
on the TiO2 surface acts as an active site of CuOx/TiO2 catalysts on the oxidative decomposition of benzene. The catalytic activity gradually increases with an increase of Cu loading
on TiO2. When Cu loading reaches 5.5 wt%, the total conversion temperature is lowered to 300 °C. However, the catalytic activity
considerably decreases at 7 wt% Cu loading. The catalytic activity increased with an increase of oxygen concentration but
the concentration of benzene showed no difference in the benzene conversion. This result suggests that the rate determining
step is the adsorption of oxygen. |
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Keywords: | CuOx/TiO2 Catalyst Benzene Catalytic Combustion VOCs TPR |
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